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WINE CHEMISTRY
Brett - Brettanomyces
Study proposed by Stephane Gorgerat |
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What is « Brett » ?
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Brettanomyces (often abridged Brett) are unicellular
yeast. Those yeasts can be found in any beverages resulting from an
alcoholic fermentation: wine, cider or bier.
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Brett
are not toxic by ingestion. However, they produce
volatile phenols which can modify the sensorial characteristics of
the wine. In this area, 4-ethylphenol (stables, barnyards and sweaty saddles
aromas), 4-ethylguiacol (smoky, spicy
aromas) and isovaleric acid (rancid, horsey aroma) are the key molecules in order of sensory importance. 4-ethylphenol is the most prominent molecule in
bretty wines and it is the one that most laboratories are looking for to indicate the presence of
Brett.
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The origin of Brett
is not clear. Nevertheless, it seems that some aspects of wine-making
do influence on the risk of contamination. Unsurprisingly,
hygiene appears to be a critical part, since yeasts have been found
on
organic leftovers in pumps used for the
transfer of the must.
Unfortunately, it seems that "modern" wine-making techniques used since the beginning of the
Nineties, may favor the presence of Brett. Decreasing the added
sulphur quantity is an aspect of these new techniques. Indeed, the most effective way of preventing Brett
is to maintain an adequate concentration of free
sulphur
dioxyde (SO2). Moreover, the new style of
extracted super-ripe grapes leads to a
lower
acidity in the
must which decreases the effect of SO2.
An other problem is the
residual
sugar
which allows
Brett
to be active after the fermentation.
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Some recent studies show that oxygen could also be linked to the presence of Brett
and that the microbullage technique favors its
expansion. However this aspect is highly controversial since others studies
have shown opposite results.
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Nevertheless, even if the above mentioned aspects are minimized during the
wine making, the number of contaminated wines seems to increase
dramatically these days. This proves that there is still a long way to go to define precisely the behaviour of
Brett
in order to eradicate it.
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The presence of
Brett
in wine is not always considered as a default.
It all depends on its concentration. A little sensation of Brett
can add some
complexity to the wine. The famous Châteauneuf-du-Pape, Château de Beaucastel
from the Southern Rhône area in France, is a perfect example of
this assertion: bottles of 1989 and 1990, both considered as outstanding vintages for this estate, were controlled positive to Brett. Of course, it is also a matter of sensibility
to the
palate which is known to vary a lot from one wine taster to another.
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Finally, one should be careful not to confuse Reduction with the presence of Brett. Reduction
is characterized by rotten egg, onion, animal or cabbage odours.
Reduction is a transitory phase which often disappears with airing.
It is to be noted that aeration has no positive effect on the
volatile phenols generated by the Brett.
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The profile of Stephane Gorgerat
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I was born
in a
vintage that will be remembered in the Bordeaux history as one of the worst of the
past 50 years: 1977..
My passion for wine began only quite recently, however the wine virus
is now expanding very rapidly! Mostly Bordeaux oriented at the
first stages of my passion for wine and
oenology, I recently diversified
my curiosity to other wine areas, i.e. Provence in Southern France or
the Valais in the Swiss Alps mountains. I am also trying to visit as
many wine estates as possible as I believe that direct contact and discussions with wine makers
undeniably helps to better assess a wine or a style.
In my professional life, I'm a chemist specialized in environmental and
organic chemistry. I am currently working
for a pharmaceutical group in Geneva where I am developing a new contrast agent for
medical diagnosis imaging.
I had the chance to know Alain through the French speaking discussion
group lapassionduvin.com. Evelyne,
aka Mrs Winemega and Alain, with whom we became close friends, asked me to confront my
professional expertise with the wine world and to write a few articles
specialized on the chemistry of wine.
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